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AP EAMCET202123 Aug 2021Morning ShiftChemistryp Block Elements (Group 13 & 14)Actual

Carbon and germanium belong to the 14 th group. The maximum coordination number of carbon is less than germanium, because of

Options

  1. Alarger size of germanium
  2. Belectronegativity difference
  3. Cavailability of low-lying d -orbitals in germanium
  4. Delectrical conductivity

Correct answer

C. availability of low-lying d -orbitals in germanium

Step-by-step solution

Coordination number of an element depends on the availability of valence shells. Since, carbon is placed in 2nd period and electronic configuration of C ₆ is 1 s^2 2 s^2 2 p^2 . It do not have vacant d -orbital. Therefore, it has covalency of 4 . While germanium is placed in 3rd period in the periodic table. Electronic configuration of Ge ₃₂ is [ Ar ] 3 d¹⁰ 4 s^2 4 p^2 . It has vacant d -orbital. Germanium can extend its coordination number.

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