AP EAMCET202123 Aug 2021Morning ShiftChemistryp Block Elements (Group 13 & 14)Actual
Carbon and germanium belong to the 14 th group. The maximum coordination number of carbon is less than germanium, because of
Options
- Alarger size of germanium
- Belectronegativity difference
- Cavailability of low-lying d -orbitals in germanium
- Delectrical conductivity
Correct answer
C. availability of low-lying d -orbitals in germanium
Step-by-step solution
Coordination number of an element depends on the availability of valence shells. Since, carbon is placed in 2nd period and electronic configuration of C ₆ is 1 s^2 2 s^2 2 p^2 . It do not have vacant d -orbital. Therefore, it has covalency of 4 . While germanium is placed in 3rd period in the periodic table. Electronic configuration of Ge ₃₂ is [ Ar ] 3 d¹⁰ 4 s^2 4 p^2 . It has vacant d -orbital. Germanium can extend its coordination number.