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AP EAMCET201921 Apr 2019Evening ShiftChemistryp Block Elements (Group 13 & 14)Actual

Which of the following reactions can be used to prepare diborane? I )     BF 3 + LiAl H 4 → ether II ) BF 3 + NaH ⟶ 450   K III )   Na 2 B 4 O 7 + H 2 O ⟶ IV )   NaBH 4 + I 2 ⟶

Options

  1. AI ,   II ,   II
  2. BII ,   III only
  3. CIII ,   IV only
  4. DI ,   II ,   IV

Correct answer

D. I ,   II ,   IV

Step-by-step solution

Binary compounds of boron and hydrogen are called boron hydrides or boranes. It can be prepared with following reaction. 4 BF 3   +   3 LiAlH 4   → ether   2 B 2 H 6   +   3 LiF   +   3 AlF 3 2 BF 3   +   6 NaH   →   B 2 H 6   +   6 NaF 2 NaBH 4   +   I 2   → B 2 H 6   +   2 NaI   +   H 2

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