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JIPMER 2019
Exam
JIPMER
Year
2019
Subject
Chemistry
Chapter
Some Basic Concepts of Chemistry

JIPMER 2019 · Chemistry · Some Basic Concepts of Chemistry

2 KHCO_3 +CO_2+H_2 O find amount of gases formed (in lit). When...

2KHCO3⟶…+CO2+H2O2 \mathrm{KHCO}_3 \longrightarrow \ldots+\mathrm{CO}_2+\mathrm{H}_2 \mathrm{O} find amount of gases formed (in lit). When amount of KHCO3\mathrm{KHCO}_3 is 33 gm .

Options

  1. A5.6
  2. B11.2
  3. C7.46
  4. D22.4

Correct answer

C. 7.46

Step-by-step solution

The given reaction is as follows 2KHCO3⟶K2CO3( g)+CO2( g)+H2O2 \mathrm{KHCO}_3 \longrightarrow \mathrm{K}_2 \mathrm{CO}_3(\mathrm{~g})+\mathrm{CO}_2(\mathrm{~g})+\mathrm{H}_2 \mathrm{O} (l) ∵2\because 2 moles of KHCO3\mathrm{KHCO}_3 gives =1 molofK2CO3∴1=1 \mathrm{~mol} of \mathrm{K}_2 \mathrm{CO}_3 \therefore 1 moles of KHCO3\mathrm{KHCO}_3 gives =1/2 molofK2CO3∴33gm(33100 mol)ofKHCO3=1 / 2 \mathrm{~mol} of \mathrm{K}_2 \mathrm{CO}_3 \therefore 33 \mathrm{gm}\left(\frac{33}{100} \mathrm{~mol}\right) of \mathrm{KHCO}_3 gives =33200=\frac{33}{200} mol of K2CO3\mathrm{K}_2 \mathrm{CO}_3 Similarly, 33gm(33100 mol)33 \mathrm{gm}\left(\frac{33}{100} \mathrm{~mol}\right) of KHCO3\mathrm{KHCO}_3 gives =33200 mol=\frac{33}{200} \mathrm{~mol} of CO2\mathrm{CO}_2 Total moles of gases =33200+33200=66200 mol=\frac{33}{200}+\frac{33}{200}=\frac{66}{200} \mathrm{~mol}1 mol of  gas =224l volume ∴66200 mol of gas =66200×22.4=7.46l.\begin{aligned} 1 \mathrm{~mol} \text{\text{ of } gas } & =224 \mathrm{l} \text{ volume } \\ \therefore \quad \frac{66}{200} \mathrm{~mol} \text{ of gas } & =\frac{66}{200} \times 22.4=7.46 \mathrm{l} .\end{aligned}$$
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