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AP EAMCET20227 Jul 2022Evening ShiftChemistryp Block Elements (Group 15, 16, 17 & 18)Actual

Which of the following represents correct order of oxidising power of halogens with water?

Options

  1. AI ₂> Br ₂> Cl ₂> F ₂
  2. BCl ₂> F ₂> Br ₂> I ₂
  3. CF ₂> Cl ₂> I ₂> Br ₂
  4. DF ₂> Cl ₂> Br ₂> I ₂

Correct answer

D. F ₂> Cl ₂> Br ₂> I ₂

Step-by-step solution

Whenever one of the halogens is involved in oxidising a species in solution, the halogen is reduced to a halide ion associated with water molecules. The following reactions illustrate this process ^ F ₂(g)+2 e⁻ 2 ~F ⁻(a q) aligned & Cl ₂(g)+2 e⁻ 2 Cl ⁻(a q) & Br ₂(l)+2 e⁻ 2 Br ⁻(a q) & I ₂(g)+2 e⁻ 2 I ⁻(a q) aligned Smaller the size of ion, higher is the energy released when the ion is hydrated. Since, the size of ions increases in the order F ⁻ Cl ⁻(a q)> Br ⁻(a q)> I ⁻(a q) Because of very high hydration enthalpy

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