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KCET2020ChemistryAlcohols Phenols and Ethers

Which of the following on heating gives an ether as major products? (P) C ₆ H ₅ CH ₂ Br + CH ₃ ONa (Q) C ₆ H ₅ ONa + CH ₃ Br (R) ( CH ₃ )₃ C - Cl + CH ₃ ONa (S) C ₆ H ₅ CH = CHCl + CH ₃ ONa

Options

  1. ABoth (R) and (S)
  2. BBoth (P) and (R)
  3. CBoth (Q) and (S)
  4. DBoth (P) and (Q)

Correct answer

D. Both (P) and (Q)

Step-by-step solution

Here, P and Q both on heating will produce ether as major product. Here, aryl halide and sodium alkanide cannot be used for preparing phenolic ethers because of very less reactivity of aryl halides.

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