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KCET2013ChemistryHydrocarbons

Methane can be converted into ethane by the reactions

Options

  1. Achlorination followed by the reaction with alcoholic KOH
  2. Bchlorination followed by the reaction with aqueous KOH
  3. Cchlorination followed by Wurtz reaction
  4. Dchlorination followed by decarboxylation

Correct answer

C. chlorination followed by Wurtz reaction

Step-by-step solution

The chlorination of methane is carried out by treating it with chlorine in presence of ultraviolet light or by heating the reaction mixture to 520-670 ~K . methane CH ₄ + Cl ₂ hv or methyl chloride CH ₃ Cl + HCl This methyl chloride react with metallic Na in presence of dry ether to form symmetrical alkane the number of carbon atoms (ethane). This reaction is called Wurtz reaction.

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