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KCET2010ChemistryHydrocarbons

9.65 C of electric current is passed through fused anhydrous magnesium chloride. The magnesium metal thus, obtained is completely converted into a Grignard reagent. The number of moles of the Grignard reagent obtained is

Options

  1. A5 10⁻⁴
  2. B1 10⁻⁴
  3. C5 10⁻⁵
  4. D1 10⁻⁵

Correct answer

C. 5 10⁻⁵

Step-by-step solution

MgCl ₂ Mg ²⁺+2 Cl ⁻ Mg ²⁺+2 e ⁻ 1 ~mol Mg (at cathode) 2 ~F (2 96500 C ) deposits Mg =1 ~mol 9.65 C (2 96500 C ) deposits Mg =1 ~mol = 1 9.65 2 96500 =5 10⁻⁵ ~mol In order to prepare Grignard reagent, one mole of Mg is used per mole of reagent obtained. Thus, by 5 10⁻⁵ ~mol Mg , 5 10⁻⁵ mole of Grignard reagent are obtained.

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