KCET2011ChemistryIonic Equilibrium
H ₂ ~S is passed into one nm ³ of a solution containing 0.1 mole of Zn ²⁺ and 0.01 mole of Cu ²⁺ till the sulphide ion concentration reaches to 8.1 10⁻¹⁹ moles. Which one of the following statements is true? [K_ sp . of ZnS and CuS are 3 10⁻²² and 8 10⁻³⁶ respectively.]
Options
- AOnly ZnS precipitates
- BBoth CuS and ZnS precipitate
- COnly CuS precipitates
- DNo precipitation occurs
Correct answer
B. Both CuS and ZnS precipitate
Step-by-step solution
The ionic product for ZnS (0.1 8.1 10⁻¹⁹ ) and for CuS (0.01 8.1 10⁻¹⁹ ) exceeds their K_ sp values. Hence, both get precipitated.