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KCET2011ChemistryIonic Equilibrium

H ₂ ~S is passed into one nm ³ of a solution containing 0.1 mole of Zn ²⁺ and 0.01 mole of Cu ²⁺ till the sulphide ion concentration reaches to 8.1 10⁻¹⁹ moles. Which one of the following statements is true? [K_ sp . of ZnS and CuS are 3 10⁻²² and 8 10⁻³⁶ respectively.]

Options

  1. AOnly ZnS precipitates
  2. BBoth CuS and ZnS precipitate
  3. COnly CuS precipitates
  4. DNo precipitation occurs

Correct answer

B. Both CuS and ZnS precipitate

Step-by-step solution

The ionic product for ZnS (0.1 8.1 10⁻¹⁹ ) and for CuS (0.01 8.1 10⁻¹⁹ ) exceeds their K_ sp values. Hence, both get precipitated.

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