AP EAMCET201822 Apr 2018Evening ShiftChemistrySolutionsActual
At T( ~K ) , the vapour pressure of pure benzene is 0.85 bar. A non-volatile, non-electrolyte substance weighing 0.5 ~g when added to 39 ~g of benzene, the vapour pressure of the solution is 0.845 bar. The molar mass (in g mol ⁻¹ ) of the substance is
Options
- A180
- B270
- C160
- D169
Correct answer
D. 169
Step-by-step solution
If, p^ = vapour pressure of pure benzene. p= vapour pressure of solution. aligned & p^ -p p = n( solute ) n( solvent = n₁ n₂ & = 0.85-0.845 0.845 = w₁ M₁ M₂ w₂ aligned where, w₁ and w₂ are masses of solute respectively and M₁, M₂ are molar masses of solute and solvent respectively. aligned & M₁= 0.5 78 0.845 0.05 39 & M₁=169 ~g ~mol ⁻¹ aligned