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Manipal MET2024ChemistryChemical Bonding and Molecular Structure

Match List-I with List-II. array lc|lc & array c List-I (Compound) array & & array c List-II (Hybridisation) array A. & CuCl ₅³⁻ & I. & s p^3 d^2 B. & MnCl ₅³⁻ & II. & d^2 s p^3 C. & XeOF ₄ & III. & d s p^3 D. & Fe ( CO )₅ & IV. & s p^3 d array Choose the correct match from the options given below

Options

  1. AA-IV, B-III, C-I, D-II
  2. BA-IV, B-III, C-II, D-I
  3. CA-IV, B-I, C-III, D-II
  4. DA-IV, B-II, C-III, D-I

Correct answer

A. A-IV, B-III, C-I, D-II

Step-by-step solution

The correct match is A-IV, B-III, C-I, D-II. Hybridisation involved in the given complexes are aligned & CuCl ₅³⁻, Cu ( II )=s p^3 d(4 s, 4 p, 4 d) & MnCl ₅³⁻, Mn ( II )=d s p^3(3 d, 4 s, 4 p) & XeOF , Xe ( VI )=s p^3 d^2(5 s, 5 p, 5 d) & Fe ( CO )₅, Fe (0)=d^2 s p^3 aligned

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