MHT CET202617 April 2026Morning ShiftChemistryAminesActual
Identify correct decreasing order of basic strength of amines
Options
- ACH ₃ NH ₂ > ( CH ₃)₂ NH > C ₆ H ₅ NH ₂ > NH ₃
- B( CH ₃)₂ NH > CH ₃ NH ₂ > NH ₃ > C ₆ H ₅ NH ₂
- CNH ₃ > CH ₃ NH ₂ > ( CH ₃)₂ NH > C ₆ H ₅ NH ₂
- DC ₆ H ₅ NH ₂ > ( CH ₃)₂ NH > CH ₃ NH ₂ > NH ₃
Correct answer
B. ( CH ₃)₂ NH > CH ₃ NH ₂ > NH ₃ > C ₆ H ₅ NH ₂
Step-by-step solution
Basic strength of amines depends on the availability of the lone pair of electrons on the nitrogen atom for protonation. In aliphatic amines, the electron-donating +I effect of alkyl groups increases the electron density on nitrogen, making them more basic than ammonia. For methylamines in aqueous solution, the combined effect of the +I effect, steric hindrance, and hydration energy results in the basic strength order: secondary > primary > tertiary. Thus, ( CH ₃)₂ NH > CH ₃ NH ₂ > NH ₃ . In aniline ( C ₆ H ₅ NH ₂