MHT CET202613 April 2026Morning ShiftChemistryAminesActual
Which from following reagents is used to prepare alkyl isocyanides from RX?
Options
- AAgCN (alco)
- BNH ₃ (alco)
- CKNO ₂
- DAgNO ₂
Correct answer
A. AgCN (alco)
Step-by-step solution
Alkyl halides react with alcoholic silver cyanide ( AgCN ) to form alkyl isocyanides as the major product. AgCN is predominantly covalent in nature, so only the nitrogen atom has a lone pair of electrons available for nucleophilic attack. This leads to the formation of an alkyl isocyanide ( RNC ). R-X + AgCN R-NC + AgX In contrast, KCN gives alkyl cyanides, KNO ₂ gives alkyl nitrites, and AgNO ₂ gives nitroalkanes. Answer: AgCN (alco)