MHT CET202525 Apr 2025Morning ShiftChemistryAminesActual
Which from following amines has lowest pK _ b value?
Options
- AC ₂ H ₅ NH ₂
- B( CH ₃ )₃ ~N
- CC ₆ H ₅ NH ₂
- DC ₆ H ₅ CH ₂ NH ₂
Correct answer
A. C ₂ H ₅ NH ₂
Step-by-step solution
Identifying the amine with the lowest pK _ b reveals the strongest base among the given options. Ethylamine ( C ₂ H ₅ NH ₂ ) is a primary aliphatic amine where the ethyl group donates electrons via the +I effect, enhancing nitrogen's electron density and basicity; pK _ b 3.25 . Trimethylamine ( ( CH ₃)₃ N ) is a tertiary aliphatic amine with significant +I effects, but steric hindrance reduces solvation of its conjugate acid, lowering basicity; pK _ b 4.20 . Aniline ( C ₆ H ₅ NH ₂ ) is an aromatic amine with resona