Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
MHT CET202523 Apr 2025Morning ShiftChemistryAminesActual

Which from following is a correct increasing order of basic strength of compounds?

Options

  1. A( CH ₃ )₂ NH < CH ₃ NH ₂ < ( CH ₃ )₃ ~N < NH ₃
  2. BNH ₃ < ( CH ₃ )₂ NH < CH ₃ NH ₂ < ( CH ₃ )₃ ~N
  3. CCH ₃ NH ₂ < ( CH ₃ )₂ NH < ( CH ₃ )₃ ~N < NH ₃
  4. DNH ₃ < ( CH ₃ )₃ ~N < CH ₃ NH ₂ < ( CH ₃ )₂ NH

Correct answer

D. NH ₃ < ( CH ₃ )₃ ~N < CH ₃ NH ₂ < ( CH ₃ )₂ NH

Step-by-step solution

The basic strength of amines in aqueous solution depends on three competing factors: inductive effects , solvation effects , and steric hindrance . Alkyl groups exert an electron-donating inductive effect (+I), increasing electron density on the nitrogen atom and enhancing basicity. Solvation stabilizes the conjugate acid through hydrogen bonding: NH ₄^+ forms 4 H-bonds, CH ₃ NH ₃^+ forms 3, ( CH ₃)₂ NH ₂^+ forms 2, and ( CH ₃)₃ NH ^+ forms only 1. Greater solvation yields stronger basicity. Steric hindrance from b

Practice Amines on Quantrex Academy →

More from Amines

Identify the final product formed when benzenamine reacts with the given reagents in the sequential order as: i. (CH₃- CO )₂ O / Pyridine. ii. Conc. HNO₃ + H₂ SO₄ & then reacted wi 2026Choose the incorrect statement. 2026A Nitrogen containing organic compound with molecular formula C₃ H₅ N undergoes the following reactions. C₃ H₅ N + Na / Hg in C₂ H₅ OH [A] [A] + CH₃ COCl / NaOH (aq) [B] [A] + CHCl 2026The reagent used in carbylamine reaction is ----------------------- and the product of the reaction will be --------------- 2026Which of the following is the correct reaction of Hinsberg's reagent with primary, secondary and tertiary amines? 2026Identify the correct order of the type of reactions taking place in this sequence: 2026The number of structural isomers possible for a compound with molecular formula C ₃ H ₉ N is: 2026Identify the name of the reaction involved in conversion of A→B and name the compound B. ( CH ₃ CN [ H ₂ O ] H ⁺ A [ H ⁺ / H ₂ O ] Cl 2 / Red Phosphorous B ) 2026 Full Amines list All MHT CET PYQs