MHT CET202522 Apr 2025Morning ShiftChemistryAminesActual
Identify strongest base from following.
Options
- ANH ₃
- BCH ₃ NH ₂
- C( CH ₃ )₂ NH
- D( CH ₃ )₃ ~N
Correct answer
C. ( CH ₃ )₂ NH
Step-by-step solution
Base strength in aqueous solution depends on the balance between inductive effects, steric hindrance, and solvation stability. Alkyl groups donate electron density through the +I effect, increasing nitrogen's basicity. However, larger alkyl groups introduce steric hindrance and reduce conjugate acid solvation through hydrogen bonding. For methyl-substituted amines: ( CH ₃)₂ NH provides optimal balance with strong inductive effect from two methyl groups, moderate steric hindrance, and adequate solvation of its conju