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MHT CET20249 May 2024Evening ShiftChemistryAminesActual

Which one of the following compounds does not react with acetyl chloride?

Options

  1. ACH ₃ CH ₂ NH ₂
  2. BCH ₃ CH ₂ CH ₂ NHCH ₃
  3. C( CH ₃ CH ₂ )₃ ~N
  4. D( CH ₃ )₃ CNH ₂

Correct answer

C. ( CH ₃ CH ₂ )₃ ~N

Step-by-step solution

Aliphatic and aromatic primary and secondary amines undergo acylation reaction as these amines contain replaceable hydrogen atoms (positively polarised H ) on the nitrogen atom. Triethylamine, i.e., ( CH ₃ CH ₂ )₃ ~N is a tertiary amine, without any replaceable H -atom. Thus, it will not react with acetyl chloride.

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