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MHT CET202521 Apr 2025Morning ShiftChemistryBiomoleculesActual

Which carbon atom of glucopyranose numbered from C -1 to C -6 is anomeric?

Options

  1. AC-5
  2. BC-6
  3. CC-2
  4. DC-1

Correct answer

D. C-1

Step-by-step solution

The anomeric carbon in cyclic sugars originates from the carbonyl carbon in the open-chain form. In glucose, an aldohexose, the aldehyde group is located at C -1 . During cyclization to form glucopyranose, the C -1 aldehyde carbon reacts with the hydroxyl group at C -5 , forming a hemiacetal. This positions C -1 as bonded to both the ring oxygen and the anomeric hydroxyl group. C -1 becomes chiral upon ring formation and serves as the anomeric carbon. The correct identification is D .

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