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AP EAMCET201726 Apr 2017Morning ShiftChemistryStructure of AtomActual

Assertion (A) : Na ⁺ and Mg ²⁺ ions are isoelectronic but the ionic radius of Na ⁺ is greater than that of Mg ²⁺ . Reason (R) : The effective nuclear charge of Na ⁺ ion is less than that of Mg ²⁺ ion.

Options

  1. ABoth (A) and (R) are correct but (R) is not the correct explanation of (A).
  2. BBoth (A) and (R) are correct and (R) is correct explanation of (A).
  3. C(A) is not correct but (R) is correct.
  4. D(A) is correct but (R) is not correct.

Correct answer

B. Both (A) and (R) are correct and (R) is correct explanation of (A).

Step-by-step solution

Na ⁺ and Mg ²⁺ are isoelectrionic species having 10 e⁻ each. But Mg ²⁺ has 12 protons while Na ⁺ has 11 protons. Hence effective nuclear charge is greater in case of Mg ²⁺ . ionic radius 1 effective nuclear charge

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