MHT CET202012 Oct 2020Morning ShiftChemistryGeneral Principles and Processes of Isolation of MetalsActual
What happens during bessemerization process of extraction of copper from copper pyrites?
Options
- AAu and Ag metals are deposited as anode mud.
- BImpurities as As and Sb are removed as volatile oxides.
- CCu is obtained by auto reduction of Cu ₂ O and Cus.
- DIron is removed in the form of slag.
Correct answer
C. Cu is obtained by auto reduction of Cu ₂ O and Cus.
Step-by-step solution
Process for extraction of copper from copper pyrite At the starting copper pyrite is roasted in a reverberatory furnace because on roasting we will get copper oxide from the copper pyrite from which the copper can be extracted by doing reduction. 2 CuFeS ₂+ O ₂ Cu ₂ ~S +2 FeS + SO ₂ Now as we know that the iron is more reactive than the copper. So, ferrous sulphide and cuprous sulphide must react with oxygen to form ferrous oxide, copper sulphur dioxide. 2 FeS +3 O ₂ 2 FeO +2 SO ₂ Cu ₂ ~S + O ₂ Cu ₂ O + FeO ₂ Cu ₂