MHT CET202613 April 2026Evening ShiftChemistryHaloalkanes and HaloarenesActual
Which of the following favors SN ^1 reaction?
Options
- AStrong nucleophile
- BNon - Polar solvent
- CBulky alkyl groups on the carbon atom attached to halogen atom
- DSmall alkyl groups on the carbon atom attached to halogen atom
Correct answer
C. Bulky alkyl groups on the carbon atom attached to halogen atom
Step-by-step solution
The S _ N 1 reaction proceeds via the formation of a carbocation intermediate in its rate-determining step. Bulky alkyl groups on the carbon atom attached to the halogen atom (such as in tertiary alkyl halides) stabilize the resulting carbocation through the +I inductive effect and hyperconjugation. Additionally, the steric crowding in the initial tetrahedral substrate is relieved when it forms a planar carbocation, which provides a driving force for the S _ N 1 mechanism. In contrast, a strong nucleophile and smal