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MHT CET202613 April 2026Evening ShiftChemistryHaloalkanes and HaloarenesActual

Which of the following favors SN ^1 reaction?

Options

  1. AStrong nucleophile
  2. BNon - Polar solvent
  3. CBulky alkyl groups on the carbon atom attached to halogen atom
  4. DSmall alkyl groups on the carbon atom attached to halogen atom

Correct answer

C. Bulky alkyl groups on the carbon atom attached to halogen atom

Step-by-step solution

The S _ N 1 reaction proceeds via the formation of a carbocation intermediate in its rate-determining step. Bulky alkyl groups on the carbon atom attached to the halogen atom (such as in tertiary alkyl halides) stabilize the resulting carbocation through the +I inductive effect and hyperconjugation. Additionally, the steric crowding in the initial tetrahedral substrate is relieved when it forms a planar carbocation, which provides a driving force for the S _ N 1 mechanism. In contrast, a strong nucleophile and smal

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