MHT CET20255 May 2025Evening ShiftChemistryHaloalkanes and HaloarenesActual
What is the order of reactivity of alkyl halides with ammonia?
Options
- AR - Cl > R - Br > R - I
- BR - Br > R - I > R - Cl
- CR-I > R-Br > R-Cl
- DR - Cl > R - I > R - Br
Correct answer
C. R-I > R-Br > R-Cl
Step-by-step solution
Reactivity of alkyl halides with ammonia depends on nucleophilic substitution mechanisms, where ammonia acts as a nucleophile. The key factor is the leaving group ability of the halide ion. Leaving group ability is inversely related to basicity. Comparing halides: iodine is the weakest base and thus the best leaving group, followed by bromine and then chlorine. This gives the order I - > Br - > Cl - for leaving group quality. Consequently, alkyl halide reactivity follows: R - I > R - B > R - Cl . Evaluating the opt