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MHT CET20255 May 2025Evening ShiftChemistryHaloalkanes and HaloarenesActual

What is the order of reactivity of alkyl halides with ammonia?

Options

  1. AR - Cl > R - Br > R - I
  2. BR - Br > R - I > R - Cl
  3. CR-I > R-Br > R-Cl
  4. DR - Cl > R - I > R - Br

Correct answer

C. R-I > R-Br > R-Cl

Step-by-step solution

Reactivity of alkyl halides with ammonia depends on nucleophilic substitution mechanisms, where ammonia acts as a nucleophile. The key factor is the leaving group ability of the halide ion. Leaving group ability is inversely related to basicity. Comparing halides: iodine is the weakest base and thus the best leaving group, followed by bromine and then chlorine. This gives the order I - > Br - > Cl - for leaving group quality. Consequently, alkyl halide reactivity follows: R - I > R - B > R - Cl . Evaluating the opt

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