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MHT CET202522 Apr 2025Morning ShiftChemistryHaloalkanes and HaloarenesActual

The reaction of bromobenzene with bromomethane and sodium metal in dry ether to give toluene is

Options

  1. AWurtz reaction
  2. BFittig reaction
  3. CFriedel crafts reaction
  4. DWurtz-fittig reaction

Correct answer

D. Wurtz-fittig reaction

Step-by-step solution

The reaction involves an aryl halide and an alkyl halide reacting with sodium metal in dry ether to produce an alkylbenzene, which characterizes the Wurtz-Fittig reaction . The general form is Ar-X + R-X + 2Na dry ether Ar-R + 2NaX . For bromobenzene and bromomethane, the reaction is C₆H₅Br + CH₃Br + 2Na dry ether C₆H₅CH₃ + 2NaBr . This distinguishes it from the Wurtz reaction (two alkyl halides), the Fittig reaction (two aryl halides), and the Friedel-Crafts reaction (uses Lewis acid catalyst, not sodium metal). T

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