Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
MHT CET202522 Apr 2025Morning ShiftChemistryHaloalkanes and HaloarenesActual

Which of the following is NOT obtained when a mixture of chloroethane and 1-chloropropane is treated with sodium metal in dry ether?

Options

  1. APropane
  2. BButane
  3. CPentane
  4. DHexane

Correct answer

A. Propane

Step-by-step solution

The Wurtz reaction couples alkyl halides with sodium metal in dry ether to form alkanes. With chloroethane and 1-chloropropane, three products form via self-coupling and cross-coupling. Let R₁ = CH₃CH₂ – (ethyl) and R₂ = CH₃CH₂CH₂ – (propyl). Self-coupling of chloroethane yields butane ( C₄H₁₀ ): R₁R₁ = CH₃CH₂CH₂CH₃ . Self-coupling of 1-chloropropane yields hexane ( C₆H₁₄ ): R₂R₂ = CH₃CH₂CH₂CH₂CH₂CH₃ . Cross-coupling yields pentane ( C₅H₁₂ ): R₁R₂ = CH₃CH₂CH₂CH₂CH₃ . Propane ( C₃H₈ ) is not formed, as it lacks a co

Practice Haloalkanes and Haloarenes on Quantrex Academy →

More from Haloalkanes and Haloarenes

With reference to the two statements Assertion and Reason, choose the correct option. Assertion: The order of reactivity towards S_N 1 reaction is: C₆ H₅- CH₂ Br > (CH₃ )₃- C - Br 2026What is the major product [Z] formed when compound [C] undergoes the following reactions: 2026Identify the compounds A and B from the following reaction sequence: 2026Identify the wrong statement from the following 2026Two statements, Assertion and Reason are given. With reference to them, choose the correct option. Assertion: Hydrolysis of 2-Bromo-2-methylpropane follows S_N1 mechanism which inv 2026Identify X, Y and Z. 2026Which one is an INCORRECT statement with regard to the following reaction? 2026The compound from which chlorobenzene cannot be prepared easily is 2026 Full Haloalkanes and Haloarenes list All MHT CET PYQs