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MHT CET202520 Apr 2025Morning ShiftChemistryHaloalkanes and HaloarenesActual

Which among the following is NOT benzylic halide ?

Options

  1. ABromophenylmethane
  2. B1-Bromo-1-phenylpropane
  3. C2-Bromo-2-phenylpropane
  4. D1-Bromo-2-phenylbutane

Correct answer

D. 1-Bromo-2-phenylbutane

Step-by-step solution

Benzylic halides are defined as compounds where a halogen atom is bonded to an sp^3 -hybridized carbon that is directly attached to an aromatic ring. Evaluating each option: A) Bromophenylmethane: C₆H₅ – CH₂ – Br The bromine is bonded to a methylene carbon directly attached to the phenyl ring, qualifying as a primary benzylic halide . B) 1-Bromo-1-phenylpropane: C₆H₅ – CHBr – CH₂CH₃ The bromine-bearing carbon is directly phenyl-substituted, making it a secondary benzylic halide . C) 2-Bromo-2-phenylpropane: C₆H₅ –

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