MHT CET202016 Oct 2020Morning ShiftChemistryHaloalkanes and HaloarenesActual
Identify the catalyst X used in following reaction? CH ₃ CH ₂ Br +2[ H ] x CH ₃- CH ₃+ HBr
Options
- ACaO ,
- BZn-Cu Couple in alcohol
- CKMnO ₄
- DK ₂ Cr ₂ O ₇
Correct answer
B. Zn-Cu Couple in alcohol
Step-by-step solution
( CH ₃ CH ₂ Br +2[ H ] [ Alcohol ] Zn - Cu ( X ) CH ₃- CH ₃+ HBr ) In alcohol, [X] is a ( Zn - Cu ) couple. When ethyl bromide is treated with the ( Zn )-Cu pair and alcohol in this reaction, ethyl bromide is converted to ethane. This is a redox reaction in a sense. In it, ethyl bromide is reduced to form an ethyl organometallic and Brwhich is then protonated by ethanol to form ethane.