MHT CET202618 April 2026Evening ShiftChemistryHydrocarbonsActual
The major product of the following reaction is
Options
- A3 - iodo - 3 - methylhexane
- B4 - iodo - 4 - methylhexane
- C3 - iodo - 4 - methylhexane
- D4 - iodo - 3 - methylhexane
Correct answer
A. 3 - iodo - 3 - methylhexane
Step-by-step solution
The given reactant is 3-methylhex-3-ene. The addition of HI to an alkene is an electrophilic addition reaction that proceeds via the formation of a carbocation intermediate. First, the electrophile H^+ attacks the double bond. This can result in two possible carbocations: 1. Protonation at C-4 yields a tertiary carbocation at C-3. 2. Protonation at C-3 yields a secondary carbocation at C-4. Since a tertiary carbocation is significantly more stable than a secondary carbocation due to greater hyperconjugation and ind