MHT CET202525 Apr 2025Evening ShiftChemistryHydrocarbonsActual
Identify 'A' in the following reaction. A Lithium amide Ethynyl lithium Bromoethane But -1- yne
Options
- AEthene
- BEthyne
- CBut-1-ene
- DBut-2-ene
Correct answer
B. Ethyne
Step-by-step solution
Reverse analysis begins with the product but-1-yne: CH ₃ CH ₂ C CH . It forms from ethynyl lithium ( Li-C CH ) and bromoethane ( CH ₃ CH ₂ Br ) via nucleophilic substitution: Li-C CH + CH ₃ CH ₂ Br CH ₃ CH ₂ C CH + LiBr Ethynyl lithium is derived from A and lithium amide: The strong base LiNH ₂ deprotonates terminal alkynes. Since ethynyl lithium is formed, A must be ethyne ( HC CH ): HC CH + LiNH ₂ Li-C CH + NH ₃ Among the options—ethene, ethyne, but-1-ene, but-2-ene— ethyne is compound A .