MHT CET202519 Apr 2025Evening ShiftChemistryHydrocarbonsActual
Cyclohexene on oxidation with KMnO ₄ in dil. H ₂ SO ₄ forms.
Options
- ACyclohexanol
- BCyclohexanone
- CHexanoic acid
- DAdipic acid
Correct answer
D. Adipic acid
Step-by-step solution
The oxidation of cyclohexene with potassium permanganate ( KMnO₄ ) in dilute sulfuric acid ( H₂SO₄ ) constitutes strong oxidative cleavage of the alkene. Cyclohexene contains two - CH = moieties at its double bond; each carbon with a hydrogen oxidizes to a carboxylic acid ( - COOH). Cleavage yields a linear chain with terminal carboxylic groups: HOOC-(CH₂)₄-COOH , known as adipic acid. Analysis of options: Cyclohexanol arises from hydration; cyclohexanone from milder oxidation or ozonolysis with reduction; hexanoic