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MHT CET202525 Apr 2025Morning ShiftChemistryHydrogenActual

Which of the following is used in preparation of hydrogen peroxide by Merck process?

Options

  1. ACaCO _ 3( ~s )
  2. BBaO ₂ 8 H ₂ O
  3. CCaCl _ 2( ~s )
  4. DNa ₂ O _ 2( aq )

Correct answer

D. Na ₂ O _ 2( aq )

Step-by-step solution

The Merck process for the preparation of hydrogen peroxide employs hydrated barium peroxide reacting with dilute sulfuric acid. BaO ₂ 8 H ₂ O _ ( s ) + H ₂ SO _ 4( aq ) BaSO _ 4( s ) + H ₂ O _ 2( aq ) + 8 H ₂ O _ ( l ) Barium sulfate precipitates, isolating hydrogen peroxide in aqueous solution. Final answer: B

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