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MHT CET202124 Sep 2021Evening ShiftChemistrySolutionsActual

The solution containing 3 ~g urea (molar mass 60 ) per dm ^3 of water and another solution containing 4.5 ~g of solute A per dm ^3 boils at same temperature, then what is molar mass of A?

Options

  1. A54 ~g ~mol ⁻¹
  2. B180 ~g ~mol ⁻¹
  3. C120 ~g ~mol ⁻¹
  4. D90 ~g ~mol ⁻¹

Correct answer

D. 90 ~g ~mol ⁻¹

Step-by-step solution

T _ b = K _ b m molality ( m )= moles of solute mass of water ( kg ) 1L H ₂ O =1 dm ^3 H ₂ O =1 ~kg H ₂ O Density of water =1 ~kg / L Boiling points are same for two solutions, aligned & T _ b ₁ = T _ b ₂ & ~m ₁= m ₂ aligned aligned & 3 / 60 1 = 4.5 / M 1 & M = 60 4.5 3 & =90 ~g / mol aligned

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