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BITSAT Chemistry Chemical Bonding and Molecular Structure 2024 BITSAT 2024 (Memory Based Paper 3)

BITSAT Chemistry Question (2024) — Solution

Question

The hybridisation scheme for the central atom includes a d-orbital contribution in

Options

  1. A. I _3^ -
  2. B. PCl _3
  3. C. NO _3^ -
  4. D. H _2 Se

Answer

A. I _3^ -

Step-by-step solution

I _3^ - is linear with central iodine atom undergoing s p^3 d-hybridisation and three lone pairs occupying equatorial position. Thus, this structure include d-orbital contribution to the hybridisation scheme. The structure is, PCl _3 structure is s p^3-hybridised with one lone pair. NO _3^ - is s p^2-hybridised and H _2 Se is s p^3 - hybridised with two lone pairs of Se atom.

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