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BITSAT Chemistry Thermodynamics (C) 2021 BITSAT 2021

BITSAT Chemistry Question (2021) — Solution

Question

Work out the heat change (cal) when 40 ~g of He gas at 27^ C undergoes isothermal and reversible compression from initial pressure of 1 ~atm to 10 ~atm ( R =2 cal K ^ -1 ~mol ^ -1 ).

Options

  1. A. 13.818 kcal
  2. B. -13.818 kcal
  3. C. 55.272 kcal
  4. D. -55.272 k cal

Answer

B. -13.818 kcal

Step-by-step solution

aligned q &=- w _ rev =- (-2.303 nRT P _ 1 P _ 2 ) \\ &=2.303 40 4 2 300 1 10 =-13.82 kcal aligned

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