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JEE Advanced Chemistry Amines 2025 JEE Advanced 2025 (Paper 1)

JEE Advanced Chemistry Question (2025) — Solution

Question

Match the compounds in List-I with the appropriate observations in List-II and choose the correct option. LIST - I LIST - II (P) (1) Reaction with phenyl diazonium salt gives #ff0 dye. (Q) (2) Reaction with ninhydrin gives purple color and it also reacts with FeCl _3 to give violet color. (R) (3) Reaction with glucose will give corresponding hydrazone. (S) (4) Lassiagne extract of the compound treated with dilute HCl followed by addition of aqueous FeCl _3 gives blood red color. (5) After complete hydrolysis,it will give ninhydrin test and it DOES NOT give positive phthalein dye test.

Options

  1. A. P 1 ; Q 5 ; R 4 ; S 2
  2. B. P 2 ; Q 5 ; R 1 ; S 3
  3. C. P 5 ; Q 2 ; R 1 ; S 4
  4. D. P 2 ; Q 1 ; R 5 ; S 3

Answer

B. P 2 ; Q 5 ; R 1 ; S 3

Step-by-step solution

(P) Gives FeCl _3 test because of presence of phenolic group and ninhydrin test. (Q) Amino acid obtained gives (+) Ninhydrin test but not phthalein dye test. (R) Reaction with phenyl diazonium salt gives yellow dye. (S) Compound will form hydrazone derivative with aldehydic group of glucose.

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