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JEE Advanced Chemistry Chemical Bonding and Molecular Structure 2025 JEE Advanced 2025 (Paper 2)

JEE Advanced Chemistry Question (2025) — Solution

Question

The correct statements (s) about intermolecular forces is(are)

Options

  1. A. The potential energy between two point charges approaches zero more rapidly than the potential energy between a point dipole and a point charge as the distance between them approaches infinity.
  2. B. The average potential energy of two rotating polar molecules that are separated by a distance r has 1 / r^3 dependence.
  3. C. The dipole-induced dipole average interaction energy is independent of temperature.
  4. D. Nonpolar molecules attract one another even though neither has a permanent dipole moment.

Answer

D. Nonpolar molecules attract one another even though neither has a permanent dipole moment.

Step-by-step solution

(i) Ion - Ion Interaction energy 1 r Ion - dipole Interaction energy 1 r^2 Ion - dipole Interaction energy approaches zero more rapidly as ' r ' increases (ii) Rotating Polar molecules Interaction energy 1 r ^6 . (iii) Dipole - induced dipole forces are independent of temperature. (iv) Non-polar species show London dispersion forces.

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