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JEE Advanced Chemistry Structure of Atom 2020 JEE Advanced 2020 (Paper 2)

JEE Advanced Chemistry Question (2020) — Solution

Question

The figure below is the plot of potential energy versus internuclear distance ( d ) of H 2 molecule in the electronic ground state. What is the value of the net potential energy E 0 (as indicated in the figure) in kJ mol - 1 , for d = d 0 at which the electron-electron repulsion and the nucleus-nucleus repulsion energies are absent? As reference, the potential energy of H atom is taken as zero when its electron and the nucleus are infinitely far apart. Use Avogadro constant as 6 .023 × 10 23 mol − 1 . Mark total potential energy for 2 H-atom (per mole) as answer.

Options

  1. A. A
  2. B. B
  3. C. C
  4. D. D

Answer

A. A

Step-by-step solution

For one H atom P . E .   =- kq 1 q 2 r =- 9 × 10 9 × 1 .6 × 10 − 19 2 0 .529 × 10 − 10 =- 9 × 1 . 6 × 1 . 6 0 . 529 × 10 - 19 Total potential energy for 2 H-atom (per mole) =- 2 × 9 × 1 .6 × 1 .6 0 .529 × 10 − 19 × 6 × 10 23 = -5246 .5   kJ / mole

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