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JEE Advanced Chemistry Surface Chemistry 2022 JEE Advanced 2022 (Paper 1)

JEE Advanced Chemistry Question (2022) — Solution

Question

The correct option(s) related to adsorption processes is(are)

Options

  1. A. Chemisorption results in a unimolecular layer.
  2. B. The enthalpy change during physisorption is in the range of 100 to 140   kJ   mol - 1 .
  3. C. Chemisorption is an endothermic process.
  4. D. Lowering the temperature favours physisorption processes.

Answer

D. Lowering the temperature favours physisorption processes.

Step-by-step solution

(A) First statement is correct as chemisorption results in a unimolecular layer and physisorption result in a multimolecular layer. (B) Second statement is incorrect as enthalpy change during physisorption is of the range of 20 - 40 kJmol - 1 .Gases with higher critical temperatures are readily adsorbed (C) Chemisorption is an exothermic process with 80 - 240 kJmol - 1 as the enthalpy of adsorption. (D) Lowering the temperature results in increase in the extent of physisorption.It decreases with increase of temperature. Hence (A) and (D) are correct.

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