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JEE Main Chemistry Chemical Bonding and Molecular Structure 2026 JEE Main 2026 (24 January Shift 2)

JEE Main Chemistry Question (2026) — Solution

Question

Pair of species among the following having same bond order as well as paramagnetic character will be-

Options

  1. A. O _ 2 ^ - , N _ 2 ^ +
  2. B. O _ 2 ^ + , N _ 2 ^ 2-
  3. C. O _ 2 ^ - , N _ 2 ^ -
  4. D. O _ 2 ^ + , N _ 2 ^ -

Answer

D. O _ 2 ^ + , N _ 2 ^ -

Step-by-step solution

Bond orders and magnetic character: O₂⁻ (BO=1.5, paramagnetic), O₂⁺ (BO=2.5, paramagnetic), O₂²⁻ (BO=1, diamagnetic); N₂⁺ (BO=2.5, paramagnetic), N₂⁻ (BO=2.5, paramagnetic), N₂²⁻ (BO=2, diamagnetic) 1 : BO 1.5 vs 2.5 (different); 2 : BO 2.5 vs 2 (different); 3 : BO 1.5 vs 2.5 (different); 4 : O₂⁺ (BO=2.5, paramagnetic) and N₂⁻ (BO=2.5, paramagnetic) - both same bond order and paramagnetic character

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