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JEE Main Chemistry Chemical Bonding and Molecular Structure 2026 JEE Main 2026 (23 January Shift 2)

JEE Main Chemistry Question (2026) — Solution

Question

Which statements are NOT TRUE about XeO _ 2 ~F _ 2 ? A. It has a see-saw shape. B. Xe has 5 electron pairs in its valence shell in XeO _ 2 ~F _ 2 . C. The O - Xe - O bond angle is close to 180^ . D. The F - Xe - F bond angle is close to 180^ . E. Xe has 16 valence electrons in XeO _ 2 ~F _ 2 . Choose the correct answer from the options given below:

Options

  1. A. B, C and E Only
  2. B. B and D Only
  3. C. A and D Only
  4. D. B, D and E Only

Answer

A. B, C and E Only

Step-by-step solution

In XeO_2F_2: Xe has 8 valence electrons forming 4 bonding pairs (2 with O, 2 with F) and 2 lone pairs, giving a trigonal bipyramidal electron geometry with a see-saw molecular shape, making statement A TRUE. Statement B is NOT TRUE because the total electron pairs around Xe is 6 (4 bonding + 2 lone), not 5. For statement C, the O-Xe-O angle in a see-saw geometry is approximately 120°, not close to 180°, making it NOT TRUE. Statement D is TRUE as the F-Xe-F angle is approximately 180° when F atoms occupy axial positions. Statement E is NOT TRUE since Xe has only 8 valence electrons, not 16. The incorrect statements are B, C, and E.

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