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JEE Main Chemistry Chemical Equilibrium 2026 JEE Main 2026 (08 April Shift 2)

JEE Main Chemistry Question (2026) — Solution

Question

Consider the following reactions in which all the reactants and products are present in gaseous state 2xy x_2 + y_2 K_1 = 2.5 10^5 xy + 1 2 z_2 xyz K_2 = 5 10^ -3 The value of K_3 for the equilibrium 1 2 x_2 + 1 2 y_2 + 1 2 z_2 xyz is:

Options

  1. A. 2.5 10^ -3
  2. B. 2.5 10^ 3
  3. C. 1.0 10^ -5
  4. D. 5 10^ -3

Answer

C. 1.0 10^ -5

Step-by-step solution

The given reactions are: 2xy x_2 + y_2 K_1 = 2.5 10^5 xy + 1 2 z_2 xyz K_2 = 5 10^ -3 We need to find the equilibrium constant K_3 for the reaction: 1 2 x_2 + 1 2 y_2 + 1 2 z_2 xyz Reversing the first reaction and multiplying it by 1 2 , we get: 1 2 x_2 + 1 2 y_2 xy The equilibrium constant for this modified reaction is: K' = ( 1 K_1 )^ 1 2 = 1 K_1 Adding this modified reaction to the second reaction: 1 2 x_2 + 1 2 y_2 xy (K') xy + 1 2 z_2 xyz (K_2) --------------------------------------------------- 1 2 x_2 + 1 2 y_2 + 1 2 z_2 xyz The equilibrium constant K_3 for the overall reaction is the product of the equilibrium constants of the added reactions: K_3 = K' K_2 = K_2 K_1 Substituting the given values: K_3 = 5 10^ -3 2.5 10^5 K_3 = 5 10^ -3 25 10^4 K_3 = 5 10^ -3 5 10^2 K_3 = 1.0 10^ -5 Answer: 1.0 10^ -5

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Related: Chemistry — Chemical Equilibrium · All PYQ Banks