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JEE Main Chemistry Classification of Elements and Periodicity in Properties 2026 JEE Main 2026 (22 January Shift 2)

JEE Main Chemistry Question (2026) — Solution

Question

Given below are two statements : Statement I : C Statement II : S > Se > Te > Po > O is the correct order in terms of the magnitude of electron gain enthalpy values. In the light of the above statements, choose the correct answer from the options given below :

Options

  1. A. Statement I is true but Statement II is false
  2. B. Statement I is false but Statement II is true
  3. C. Both Statement I and Statement II are false
  4. D. Both Statement I and Statement II are true

Answer

D. Both Statement I and Statement II are true

Step-by-step solution

Statement I: Ionization enthalpy generally increases across a period from left to right. However, Nitrogen (2s^2 2p^3) has a stable half-filled electronic configuration, making it harder to remove an electron compared to Oxygen (2s^2 2p^4). Thus, the order is C Statement I is true. Statement II: For Group 16 elements, Oxygen has an exceptionally low magnitude of electron gain enthalpy due to its small size and high inter-electronic repulsions in the 2p subshell. The magnitude of electron gain enthalpy decreases down the group from Sulphur onwards. The correct order of magnitude is S > Se > Te > Po > O. Statement II is true. Both statements are correct.

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Related: Chemistry — Classification of Elements and Periodicity in Properties · All PYQ Banks