Number of paramagnetic ions among the following d- and f-block metal ions is _______. Mn^ 2+ , Cu^ 2+ , Zn^ 2+ , Yb^ 2+ , Sc^ 3+ , La^ 3+ , Gd^ 3+ , Lu^ 3+ , Ti^ 4+ , Ce^ 4+ (Atomic number of Mn = 25, Cu = 29, Zn = 30, Yb = 70, Sc = 21, La = 57, Gd = 64, Lu = 71, Ti = 22, Ce = 58)
A. A
The magnetic nature of an ion depends on the presence of unpaired electrons. Ions with at least one unpaired electron are paramagnetic, while those with all paired electrons are diamagnetic. Let us write the electronic configurations of the given ions: Mn^ 2+ (Z=25) : [Ar] 3d^5 5 unpaired electrons (Paramagnetic) Cu^ 2+ (Z=29) : [Ar] 3d^9 1 unpaired electron (Paramagnetic) Zn^ 2+ (Z=30) : [Ar] 3d^ 10 0 unpaired electrons (Diamagnetic) Yb^ 2+ (Z=70) : [Xe] 4f^ 14 0 unpaired electrons (Diamagnetic) Sc^ 3+ (Z=21) : [Ar] 3d^0 0 unpaired electrons (Diamagnetic) La^ 3+ (Z=57) : [Xe] 4f^0 0 unpaired electrons (Diamagnetic) Gd^ 3+ (Z=64) : [Xe] 4f^7 7 unpaired electrons (Paramagnetic) Lu^ 3+ (Z=71) : [Xe] 4f^ 14 0 unpaired electrons (Diamagnetic) Ti^ 4+ (Z=22) : [Ar] 3d^0 0 unpaired electrons (Diamagnetic) Ce^ 4+ (Z=58) : [Xe] 4f^0 0 unpaired electrons (Diamagnetic) The paramagnetic ions are Mn^ 2+ , Cu^ 2+ , and Gd^ 3+ . Total number of paramagnetic ions = 3. Answer: 3
Related: Chemistry — d and f Block Elements · All PYQ Banks