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JEE Main Chemistry d and f Block Elements 2026 JEE Main 2026 (28 January Shift 1)

JEE Main Chemistry Question (2026) — Solution

Question

Given below are two statements: Statement I : The number of pairs, from the following, in which both the ions are coloured in aqueous solution is 3. [ Sc ^ 3+ , Ti ^ 3+ ], [ Mn ^ 2+ , Cr ^ 2+ ], [ Cu ^ 2+ , Zn ^ 2+ ] and [ Ni ^ 2+ , Ti ^ 4+ ] Statement II : Th ^ 4+ is the strongest reducing agent among Th ^ 4+ , Ce ^ 4+ , Gd ^ 3+ and Eu ^ 2+ . In the light of the above statements, choose the correct answer from the options given below

Options

  1. A. Both Statement I and Statement II are false
  2. B. Both Statement I and Statement II are true
  3. C. Statement I is false but Statement II is true
  4. D. Statement I is true but Statement II is false

Answer

A. Both Statement I and Statement II are false

Step-by-step solution

[Sc³⁺, Ti³⁺] has Sc³⁺ colorless (no d-electrons) and Ti³⁺ colored; [Mn²⁺, Cr²⁺] has Mn²⁺ colorless (d⁵ half-filled, no d-d transitions) and Cr²⁺ colored; [Cu²⁺, Zn²⁺] has Cu²⁺ colored and Zn²⁺ colorless (d¹⁰ filled); [Ni²⁺, Ti⁴⁺] has Ni²⁺ colored and Ti⁴⁺ colorless (no d-electrons). Zero pairs have both ions colored. Statement I is FALSE. Th⁴⁺ is not a reducing agent. Statement II is FALSE. Both statements are false.

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