Quantrex Academy · Free JEE Main PYQ solutions
JEE Main Chemistry General Organic Chemistry 2026 JEE Main 2026 (06 April Shift 2)

JEE Main Chemistry Question (2026) — Solution

Question

Shown below is the structure of methyl acetate with three different , and carbon - oxygen bonds. The correct order of bond lengths of these bonds is :

Options

  1. A. > >
  2. B. < <
  3. C. = =
  4. D. < =

Answer

B. < <

Step-by-step solution

In methyl acetate, the bond is a C=O double bond, which is the shortest among the three. The bond is a C-O single bond adjacent to a carbonyl group. Due to resonance (CH_3-C(=O)-O-CH_3 CH_3-C(-O^-)=O^+-CH_3), the bond acquires partial double bond character, making it shorter than a pure single bond. The bond is a pure C-O single bond between an sp^3 hybridized carbon and oxygen, with no resonance involvement. Thus, it is the longest bond. Therefore, the correct order of bond lengths is Answer: < <

Practice more on Quantrex App →

Related: Chemistry — General Organic Chemistry · All PYQ Banks