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MHT CET Chemistry Alcohols Phenols and Ethers 2026 MHT CET 2026 (20 April Shift 1)

MHT CET Chemistry Question (2026) — Solution

Question

Identify product 'B' in following series of reactions 2-methylpropan-2-ol [ 363\ K ] 20\%\ H _2 SO _4 A [ Conc. H _2 SO _4 ] H _2 O \ \ B

Options

  1. A. n-Butylalcohol
  2. B. sec-Butylalcohol
  3. C. Iso-butylalcohol
  4. D. tert-Butylalcohol

Answer

D. tert-Butylalcohol

Step-by-step solution

The starting material, 2-methylpropan-2-ol, is a tertiary alcohol. On heating with 20\% H_2SO_4 at 363\ K , it undergoes acid-catalyzed dehydration to form an alkene, 2-methylpropene (product A). (CH_3)_3C-OH H^+, (CH_3)_2C=CH_2 + H_2O Product A is 2-methylpropene. When 2-methylpropene is treated with water in the presence of concentrated H_2SO_4 and heat, it undergoes acid-catalyzed hydration. The addition of water follows Markovnikov's rule, proceeding via the formation of a stable tertiary carbocation. (CH_3)_2C=CH_2 + H^+ (CH_3)_3C^+ (CH_3)_3C^+ + H_2O (CH_3)_3C-OH + H^+ The final product B is 2-methylpropan-2-ol, which is commonly known as tert-butyl alcohol. Answer: tert-Butylalcohol

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