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MHT CET Chemistry Alcohols Phenols and Ethers 2026 MHT CET 2026 (19 April Shift 1)

MHT CET Chemistry Question (2026) — Solution

Question

Identify the compound obtained when ethyl methyl ketone is treated with CH _3 MgBr and hydrolyzed.

Options

  1. A. ( CH _3)_3 C - OH
  2. B. C _2 H _5 - CH _3 | CH _3 | C - OH
  3. C. ( C _2 H _5)_3\, C - OH
  4. D. CH _3 - C _2 H _5 | C _2 H _5 | C - OH

Answer

B. C _2 H _5 - CH _3 | CH _3 | C - OH

Step-by-step solution

Ethyl methyl ketone is CH _3- CO - C _2 H _5. When it reacts with the Grignard reagent CH _3 MgBr , the nucleophilic methyl group attacks the electrophilic carbonyl carbon to form an intermediate alkoxide. CH _3- CO - C _2 H _5 + CH _3 MgBr CH _3- C ( OMgBr )( CH _3)- C _2 H _5 Upon hydrolysis, the alkoxide is protonated to yield a tertiary alcohol. CH _3- C ( OMgBr )( CH _3)- C _2 H _5 H _2 O C _2 H _5- C ( CH _3)_2- OH + Mg ( OH ) Br The final product is 2-methylbutan-2-ol, which matches the structure C _2 H _5 - CH _3 | CH _3 | C - OH . Answer: C _2 H _5 - CH _3 | CH _3 | C - OH

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