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MHT CET Chemistry Alcohols Phenols and Ethers 2026 MHT CET 2026 (16 April Shift 2)

MHT CET Chemistry Question (2026) — Solution

Question

Which of the following reagents limits the oxidation of R-CH _2 OH up to R-CHO only?

Options

  1. A. PCC
  2. B. CrO _3
  3. C. K _2 Cr _2 O _7 / dil. H _2 SO _4
  4. D. KMnO _4 (acidic)

Answer

A. PCC

Step-by-step solution

Primary alcohols ( R-CH _2 OH ) can be oxidized to aldehydes ( R-CHO ) or carboxylic acids ( R-COOH ) depending on the oxidizing agent used. Strong oxidizing agents like acidic KMnO _4, K _2 Cr _2 O _7 / dil. H _2 SO _4, and CrO _3 in aqueous medium oxidize primary alcohols directly to carboxylic acids. To limit the oxidation to the aldehyde stage, mild oxidizing agents are required. Pyridinium chlorochromate (PCC) is a mild oxidizing agent that selectively oxidizes primary alcohols to aldehydes and prevents further oxidation to carboxylic acids. R-CH _2 OH PCC R-CHO Answer: PCC

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