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MHT CET Chemistry Alcohols Phenols and Ethers 2026 MHT CET 2026 (15 April Shift 2)

MHT CET Chemistry Question (2026) — Solution

Question

Identify the name of reaction when phenol reacts with chloroform in aqueous NaOH.

Options

  1. A. Kolbe's reaction
  2. B. Reimer-Tiemann reaction
  3. C. Williamson synthesis
  4. D. Friedel-Crafts acylation

Answer

B. Reimer-Tiemann reaction

Step-by-step solution

When phenol is treated with chloroform (CHCl_3) in the presence of aqueous sodium hydroxide (NaOH), an aldehyde group (-CHO) is introduced at the ortho position of the benzene ring. This reaction results in the formation of salicylaldehyde (2-hydroxybenzaldehyde) as the major product. This electrophilic substitution reaction, which proceeds via a dichlorocarbene (:CCl_2) intermediate, is known as the Reimer-Tiemann reaction. Answer: Reimer-Tiemann reaction

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