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MHT CET Chemistry Aldehydes and Ketones 2026 MHT CET 2026 (18 April Shift 2)

MHT CET Chemistry Question (2026) — Solution

Question

Identify the 'product' in the following reaction. Pent - 3 - enenitrile [ H _3 O ^+ ] Al H (i-Bu) _2 Product

Options

  1. A. Pent - 3 - en - 1 - amine
  2. B. Pentanal
  3. C. Pent - 3 - enal
  4. D. Pent - 3 - en -1 - ol

Answer

C. Pent - 3 - enal

Step-by-step solution

The given reactant is pent-3-enenitrile, which has the structure CH _3- CH = CH - CH _2- CN . Diisobutylaluminium hydride (DIBAL-H), represented as AlH(i-Bu) _2, is a selective reducing agent. It reduces nitriles to imines at low temperatures, which upon subsequent acidic hydrolysis ( H _3 O ^+) yield aldehydes. DIBAL-H does not reduce isolated carbon-carbon double bonds. The reaction proceeds as follows: CH _3- CH = CH - CH _2- C N AlH(i-Bu) _2 CH _3- CH = CH - CH _2- CH = N - Al(i-Bu) _2 CH _3- CH = CH - CH _2- CH = N - Al(i-Bu) _2 H _3 O ^+ CH _3- CH = CH - CH _2- CHO The final product is pent-3-enal. Answer: Pent - 3 - enal

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