Question
Propyne on reaction with water in presence of 40\% sulphuric acid and 1\% mercuric sulphate forms
Propyne on reaction with water in presence of 40\% sulphuric acid and 1\% mercuric sulphate forms
C. Propanone
Propyne undergoes hydration in the presence of dilute sulphuric acid and mercuric sulphate according to Markovnikov's rule. The addition of a water molecule to the triple bond initially yields an unstable enol intermediate, prop-1-en-2-ol. CH_3-C CH + H_2O Hg^ 2+ , H^+ CH_3-C(OH)=CH_2 The enol intermediate rapidly undergoes tautomerization to form the more stable keto form, propanone. CH_3-C(OH)=CH_2 CH_3-CO-CH_3 Answer: Propanone
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