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MHT CET Chemistry Aldehydes and Ketones 2026 MHT CET 2026 (18 April Shift 1)

MHT CET Chemistry Question (2026) — Solution

Question

Identify the reagent 'R' used in the following reaction C _6 H _5 COCl R C _6 H _5 CHO + HCl

Options

  1. A. CO , HCl
  2. B. H _2, Pd - BaSO _4
  3. C. DIBAl - H
  4. D. H _2 O

Answer

B. H _2, Pd - BaSO _4

Step-by-step solution

The given reaction is the conversion of benzoyl chloride ( C _6 H _5 COCl ) to benzaldehyde ( C _6 H _5 CHO ). This transformation is known as the Rosenmund reduction. The reagent used for this reaction is hydrogen gas in the presence of a palladium catalyst supported on barium sulfate ( H _2, Pd - BaSO _4). The barium sulfate acts as a catalytic poison that partially deactivates the palladium, preventing the further reduction of the newly formed aldehyde into an alcohol. Thus, the reagent 'R' is H _2, Pd - BaSO _4. Answer: H _2, Pd - BaSO _4

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